PAN
Metal Indicator
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Product codeP002 PAN
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CAS No.85-85-8
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Chemical name1-(2-Pyridylazo)-2-naphthol
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MWC15H11N3O=249.27
Unit size | Price | FUJIFILM Wako Products code |
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1 g | ¥8,800 | 344-02131 |
Product Description
PAN is a metal indicator and colorimetric reagent for heavy metal and rare earth metal ions. This reagent is slightly soluble in acidic solutions and soluble in alkaline solutions. Its proton dissociation constants are reported to be pKa1=2.9 and pKa2=11.6 (μ=0.1, NaClO4, at room temperature). The aqueous solution is yellow at pH<12 and red at pH>12. The distribution constants, logKD, of chloroform/water and carbon tetrachloride/water are reported to be 5.4 and 4.0, respectively.
Chemical Structure
Technical info
Table 1 Characteristics of PAN Metal Complex
* M=metal ion, L=PAN
Table 2 Photometric Detection Conditions Using PAN
References
1. S. Shibata, Solvent Extraction Behavior of Some Metal-1-(2-Pyridylazo)-2-naphthol Chelates. Anal Chim Acta. 1960;23:367-369.
Handling and storage condition
Appearance: | Yellowish orange to reddish orange powder or crystalline powder |
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Solubility in Methyl alcohol: | To pass test (clear, yellowish orange) |
Absorbance: | ≧ 0.600 (around 470 nm) |
m.p.: | 138 - 145℃ |
Sulfated ash: | ≦ 1.00 % |
Sensitivity: | To pass test |
IR spectrum: | Authentic |
Ambient temperature |